π-сопряженные 4,6-дизамещенные пиримидины на основе 2-амино-4,6-диметилпиримидина: синтез и исследование их оптических и электрохимических характеристик
DOI:
https://doi.org/10.17072/2223-1838-2019-2-171-183Аннотация
Синтезирован ряд 4,6-дизамещенных 2-аминопиримидинов, содержащих протяженную цепь сопряжения, исследованы их оптические и электрохимические свойства. Показано, что соединениям свойственен положительный сольватохромизм, ацидохромизм, а также низкие значения потенциалов окисления, 2-амино-4,6-ди(2-гетарилвинил)пиримидины, включающие 1-метил-1Н-пиррольный и 10-гексил-10Н-фенотиазиновые фрагменты обладают низкой шириной запрещенной зоны: Egopt = 1,75 эВ (ТГФ) и 1.93 эВ (CHCl3); Egelc =1,11 и 0. 88 эВ, соответственноБиблиографические ссылки
Библиографический список
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References
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