π-сопряженные 4,6-дизамещенные пиримидины на основе 2-амино-4,6-диметилпиримидина: синтез и исследование их оптических и электрохимических характеристик
DOI:
https://doi.org/10.17072/2223-1838-2019-2-171-183Abstract
Синтезирован ряд 4,6-дизамещенных 2-аминопиримидинов, содержащих протяженную цепь сопряжения, исследованы их оптические и электрохимические свойства. Показано, что соединениям свойственен положительный сольватохромизм, ацидохромизм, а также низкие значения потенциалов окисления, 2-амино-4,6-ди(2-гетарилвинил)пиримидины, включающие 1-метил-1Н-пиррольный и 10-гексил-10Н-фенотиазиновые фрагменты обладают низкой шириной запрещенной зоны: Egopt = 1,75 эВ (ТГФ) и 1.93 эВ (CHCl3); Egelc =1,11 и 0. 88 эВ, соответственноReferences
Библиографический список
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References
Hadad C., Achelle S., García-Martinez J.C., Rodríguez-Lopez J. (2011), “4-Arylvinyl-2,6-di(pyridin-2-yl)pyrimidines: Synthesis and Optical Properties”, Journal of Organic Chemistry. Vol. 76, no. pp.3837-3845.
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Mamtimin X., Aikebaierjiang A., Alifujiang M., Tuerxun T., Kurban Z., Sun W. F., Nurulla I. (2011), Synthesis, characterization and acidochromism of Poly (2-N,N–dimethylamino-4,6-Bis (2-thienyl)-pyrimidine), Journal of Polymer Research. Vol. 1, no. 1. pp. 105-109.
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Li K.-C., Hsu Y.-C., Lin J.-T., Yang C.-C., Wei K.-H., Lin H.-C. (2008), “Novel Narrow-Band-Gap Conjugated Copolymers Containing Phenothiazine-Arylcyanovinyl Units for Organic Photovoltaic Cell Applications”, Journal of Polymer Science: Part A: Polymer Chemistry. 2008. Vol.46, no. 13. pp. 4285-4301
