Synthesis and optical properties of new 4-substituted pyrimidines - D-A type chromophores
DOI:
https://doi.org/10.17072/2223-1838-2021-2-139-153Keywords:
pyrimidine, arylmethylketone, hetarylmethylketone, three-component synthesis, chromophore, forbidden band gapAbstract
The set of 4-aryl(hetaryl)pyrimidines, where aryl/hetaryl is a highly electron donating substituent was synthesized. Optical and electrochemical properties of the synthesized compounds were studied and the values of a forbidden band gap energy ( ) were determined. The narrowest bandgap was found to be inherent to 4-ferrocenylpyrimidine (1.8 eV) and the most long-wavelength emission maximum ‑ to para-substituted pyrimidine which structure embeds a thiophene moiety between N-hexylcarbazolyl fragment and the pyrimidine core (577 нм).References
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