Синтез и оптические свойства 4-арилпиримидинов хромофоров D-A типа
DOI:
https://doi.org/10.17072/2223-1838-2021-2-139-153Ключевые слова:
пиримидин, арилметилкетон, гетарилметилкетон, трехкомпонентная реакция, хромофор, ширина запрещенной зоныАннотация
Однореакторной трехкомпонентной конденсацией арилметилкетонов с триэтилортоформиатом и ацетатом аммония как источника атомов азота синтезирован ряд 4-арилпиримидинов, в которых арил ‑ это сильный электронодонорный заместитель, исследованы их оптические свойства, определены значения оптической ширины запрещенной зоны ( ). Показано, что наиболее низким значением 1.8 эВ), обладает 4-ферроценилпиримидин, а наиболее длинноволновым максимумом испускания ( = 577 нм) ‑ 4-замещенный пиримидин, в котором между карбазольным фрагментом и пиримидиновым циклом находится тиофеновый цикл.Библиографические ссылки
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