Об экстремумах на зависимости сопротивления переноса заряда в реакции выделения водорода от потенциала электрода
DOI:
https://doi.org/10.17072/223-1838-2021-2-154-164Ключевые слова:
реакция выделения водорода, механизм Фольмера – Гейровского, сопротивление переноса заряда, кинетические параметрыАннотация
Дан анализ формы кривых «сопротивление переноса заряда – перенапряжение» для реакции выделения водорода, протекающей по механизму Фольмера – Гейровского.. Показано, что, в зависимости от соотношения кинетических параметров стадий реакции, возможны три случая: 1) экстремумы на этих кривых отсутствуют; 2) имеется один максимум; 3) имеются минимум и максимум. Обсуждаются способы определения кинетических параметров из кривых с экстремумами.Библиографические ссылки
Список литературы
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References
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