INVESTIGATION OF CALCIUM SULFATE PRECIPITATION INHIBITION BY SODIUM CARBOXYMETHYLCELLULOSE AND POLYACRYLAMIDE

Authors

  • Наталья Сергеевна Кистанова Пермский государственный национальный исследовательский университет http://orcid.org/0000-0002-3423-8709
  • Павел Юрьевич Леонтьев Пермский государственный национальный исследовательский университет
  • Ольга Станиславовна Кудряшова Естественнонаучный институт Пермского государственного исследовательского университета

DOI:

https://doi.org/10.17072/2223-1838-2019-3-203-211

Keywords:

calcium sulfate, gypsum, inhibitors of crystallization, carboxymethylcellulose, polyacrylamide

Abstract

The influence of concentration inhibitors, calcium/sulfate ratios on the precipitation of calcium sulfate was studied. The efficiency of inhibition in the presence of carboxymethylcellulose and polyacrylamide was estimated from measurements of the calcium concentration in the supersaturated solutions during the precipitation process by the standard procedure of complexometric titration. Sodium carboxymethylcellulose with the degree of polymerization of 1000 units was found to be the most effective in preventing the crystallization gypsum. Polymer concentrations as low as 0,5 g/L increases induction time, preceding the formation of the gypsum to 200 min; 1,0 g/L increased to 600 min. Mixing of equal volumes of stock solutions of calcium chloride and sodium sulfate results in final concentration 24 g gypsum per litre solution.

Author Biographies

Наталья Сергеевна Кистанова, Пермский государственный национальный исследовательский университет

Доцент, кафедра неорганической химии, химической технологии и техносферной безопасности

Павел Юрьевич Леонтьев, Пермский государственный национальный исследовательский университет

Бакалавр, кафедра неорганической химии, химической технологии и техносферной безопасности

Ольга Станиславовна Кудряшова, Естественнонаучный институт Пермского государственного исследовательского университета

Доктор химических наук, профессор

References

Перельман А.И. Геохимия. М.: Высшая школа, 1989. 582 с.

Баюрова Ю.Л., Нестеров Д.П., Корнева Е.А., Светлов А.В., Макаров Д.В., Маслобоев В.А. Искусственные геохимические барьеры для решения экологических и технологических за-дач // Вестник МГТУ. 2013. Т. 16. №3. С. 536–541.

Максимович Н.Г. Очистка сточных вод россыпных месторождений с помощью механиче-ских геохимических барьеров // Горный журнал. 2007. № 4. С. 77–78.

Каймин Е.П., Захарова Е.В., Константинова Л.И., Зубков А.А., Данилов В.В. Использова-ние кремневой кислоты для создания противофильтрационной завесы в песчаном горизон-те // Геология. 2007. № 2. С. 137–142.

Fu H., Guan B., Jiang G., Yates M.Z., Wu Z. Effect of supersaturation on competitive nuclea-tion of CaSO4 phases in a concentrated CaCl2 solution // Crystal Growth & Design. 2012. Vol. 12. P. 1388–1394.

Ahmed S.B., Tlili M.M., Amami M., Amor M.B. Gypsum Precipitation Kinetics and solubility in the NaCl-MgCl2-CaSO4-H2O system // Industrial & Engineering Chemistry Research. 2014. Vol. 53. P. 9554–9560.

Sheikholeslami R., Ong H.W.K. Kinetics and thermodynamics of calcium carbonate and calcium sulfate at salinities up to 1.5 M // Desalination. 2003. Vol. 157. P. 217–234.

Hamdona S.K., Hadad O.A. Influence of additives on the precipitation of gypsum in sodium chloride solutions // Desalination. 2008. Vol. 228. P. 277–286.

Hamdona S.K., Nessim R.B., Hamza S.M. Spontaneous precipitation of calcium sulphate dihy-drate in the presence of some metal ions // Desalination. 1993. Vol. 94. P. 69–80.

Ziegenbalg G. Grouting with mineral-forming solutions – a new technique for sealing porous and fractured rock by directed crystallization processes // Developments in Water Science. Un-derground injection Science and Technology. 2005. Vol.52. P. 341–358.

Chen T., Chen P., Montgomerie H., Hagen T. New product development for oil field application // Mineral Scales and Deposits. Scientific and Technological Approaches. Amsterdam, 2015. P. 223–238.

Ziegenbalg G. Directed and controlled crystallisation of slightly soluble Minerals – a new tech-nology to seal water inflows and to immobilize contaminants // 10th International Mine Water Association Congress. Karlsbad, Czech Republic. 2-5 June, 2008. Proceedings. P. 55–58.

Zhao Y., Jia L., Liu K., Gao P., Ge H., Fu L. Inhibition of calcium sulfate scale by poly (citric acid) // Desalination. 2016. Vol. 392. P. 1–7.

Rabizadeh T., Peacock C.L., Benning L.G. Carboxylic acids: effective inhibitors for calcium sulfate precipitation? // Mineralogical Magazine. 2014. Vol. 78(6). P. 1465–1472.

Akyol E., Öner M., Barouda E., Demadis K.D. Systematic structural determinants of the effects of tetraphosphonates on gypsum crystallization // Grystal Growth & Design. 2009. Vol. 9. 5145–5154.

Chauhan K., Kumar R., Kumar M., Sharma P., Chauhan G.S. Modified pectin-based polymers as green antiscalants for calcium inhibition // Desalination. 2012. Vol. 305. P. 31–37.

Hasson D., Shemer H., Sher A. State of the art of friendly «green» scale control inhibitors: a re-view article // Industrial & Engineering Chemistry Research. 2011. Vol. 50. P. 7601–7607.

Amjad Z., Landgraf R.T., Pen J.L. Calcium sulfate dihydrate (gypsum) scale inhibition by PAA, PAPEMP, and PAA/PAPEMP blend // International Journal of Corrosion and Scale Inhibition. 2014. Vol. 3. P. 35–47.

McCartney E.R., Alexander A.E. The effect of additives upon the process of crystallization. I. Crystallization of calcium sulfate // Journal of Colloid Science. 1958. Vol. 13. P. 383–396.

Rolfe P.F. Polymers that inhibit the deposition of calcium sulphate: some interesting conduct-ance observations // Desalination. 1966. Vol. 1. P. 359–366.

Lioliou M.G., Paraskeva C.A., Koutsoukos P.G., Payatakes A.C. Calcium sulfate precipitation in the presence of water-soluble polymers // Journal of Colloid and Interface Science. 2006. Vol. 303. P. 164–170.

Freyer D., Voigt W. Crystallization and phase stability of CaSO4 and CaSO4 – based salts // Monatshefte für Chemie. 2003. Vol. 134. P. 693–719.

Driessche A.E.S., Kellermeier M., Benning L.G., Gebauer D. Calcium sulfate precipitation throughout its phase diagram. New Perspectives on Mineral Nucleation and Growth: From So-lution Precursors to Solid Materials. Springer. 2017. P. 227–256.

Solomon D.H., Rolfe P.F. Polymers that inhibit the deposition of calcium sulphate // Desalina-tion. 1966. Vol. 1. P. 260–266.

Weijnen M.P.C., Rosmalen G.M. The influence of various polyelectrolytes on the precipitation of gypsum // Desalination. 1985. Vol. 54. P. 239–261.

Published

2019-10-11

How to Cite

Кистанова, Н. С., Леонтьев, П. Ю., & Кудряшова, О. С. (2019). INVESTIGATION OF CALCIUM SULFATE PRECIPITATION INHIBITION BY SODIUM CARBOXYMETHYLCELLULOSE AND POLYACRYLAMIDE. Bulletin of Perm University. CHEMISTRY, 9(3). https://doi.org/10.17072/2223-1838-2019-3-203-211

Issue

Section

Physical chemistry and electrochemistry